Effective collision

有效碰撞

Explanation (EN)

A non-elastic collision in which molecules of high kinetic energy overcome repulsion, interpenetrate, and react. [Ch.13 extension: requires both sufficient kinetic energy (E_kin > Ea) and correct molecular orientation (probability p), giving rate = p·f·Z.]

Explanation (ZH)

高动能分子克服排斥、相互穿透并发生反应的非弹性碰撞。【第13章扩展:既需足够动能(E_kin > Ea)又需正确的分子取向(概率 p),故 rate = p·f·Z。】

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